福建省先进材料化工基础重点实验室

华瑞茂 教授

联系方式:清华大学化学系  北京  100084

Tel.: +86-10-62792596; Fax: +86-10-62771149

E-mail: ruimao@mail.tsinghua.edu.cn

教育背景

1992-1996  Ph. D. 东京工业大学 (日本)

1986-1989  M. Sc. 中国科学院大连化学物理研究所

1982-1986  B. Sc. 福建师范大学化学系

工作履历

1989-1992 中国科学院大连化学物理研究所 助理研究员

1996-2002  Japan Science and Technology Corporation (JSP), Research Fellow

2002-现在  清华大学化学系 教授

学术兼职

目前是国际学术杂志Current Organic Synthesis、Current Catalysis、Mini-Reviews in Organic Chemistry、Journal of Chemistry and Applications编委、Reports in Organic Chemistry名誉编委;国内《精细化工》、《液晶与显示》杂志编委;中国化学会催化学会均相催化专业委员会委员 (2011-)。曾经是国际学术杂志Catalysis Communications编委、中国区副编辑 (2005-2012)。

研究领域

炔烃化学、有机材料化学

学术成果

研究团队主要从事:(1) 基于炔烃为原料的原子经济性或高原子利用率有机合成方法学研究;(2) 液晶、OLED等显示用有机材料分子的设计与合成应用基础研究。建立了一系列高效、高选择性构建具有生物活性、特殊光电性质的官能团化有机分子骨架的新反应和新方法。发表SCI学术论文100多篇,被引用1600余次,h因子29;授权国内、外发明专利122项,在申请发明专利54项。

近年发表论文

1.    Liyao Zheng, Yunhui Bin, Yunpeng Wang, Ruimao Hua*

Synthesis of Natural Product-like Polyheterocycles via One-Pot Cascade Oximation, C-H Activation and Alkyne Annulation.

       The Journal of Organic Chemistry 2016, 81, 8911-8919

2.    Biao Guo, Liyao Zheng, Lei Zhang, Ruimao Hua*

Synthesis of Benzofulvene Derivatives from Diarylacetylenes via Pd(II)-Catalyzed Alkyne-Directed C(sp2)-H Bond Activation.

The Journal of Organic Chemistry 2015, 80, 8430-8434

3.    Biao Guo, Yiming Zhou, Lei Zhang, Ruimao Hua*

Bronsted Acid-Promoted One-Pot Synthesis of Chrysene Derivatives       via Isochromenylium Intermediate Formed in Situ.

The Journal of Organic Chemistry 2015, 80, 7635-7641

4.    Lei Zhang, Liyao Zheng, Biao Guo, Ruimao Hua*

One-Pot Synthesis of Multisubstituted 2-Aminoquinolines from Annulation of 1-Aryl Tetrazoles with Internal Alkynes via Double C-H Activation and Denitrogenation.

       The Journal of Organic Chemistry 2014, 79, 11541-11548

5.    Biao Guo, Liyao Zheng, Lichen Yang, Ruimao Hua*

Synthesis of Chrysene Derivatives via Copper-Catalyzed One-Pot Dimerization of 2-Alkynyl-1-acetylbenzenes.

The Journal of Organic Chemistry 2014, 79, 4352-4357

6.    Liyao Zheng, Ruimao Hua*

Modular Assembly of Ring-Fused and π-Extended Phenanthroimidazoles via C-H Activation and Alkyne Annulation.

The Journal of Organic Chemistry 2014, 79, 3930-3936

7.    Liyao Zheng, Jia Ju, Yunhui Bin, Ruimao Hua*

Synthesis of Isoquinolines and Heterocycle-Fused Pyridines via Three-Component Cascade Reaction of Aryl Ketones, Hydroxylamine, and Alkynes.

The Journal of Organic Chemistry 2012, 77, 5794-5800

8.    Jie Li, Ruimao Hua*, Tao Liu

Highly Chemo- and Stereoselective Palladium-Catalyzed Transfer Semihydrogenation of Internal Alkynes Affording cis-Alkenes.

The Journal of Organic Chemistry 2010, 75, 2966-2970

9.    Ming Li, Ruimao Hua*

Ru3(CO)12-Catalyzed Reactions of Catechols with Alkynes: An Atom-Economic Process for the Synthesis of 2,2-Disubstituted 1,3-Benzodioxoles from the Double Addition of the O-H Bond Across a Triple Bond.

The Journal of Organic Chemistry 2008, 73, 8658-8660

10.  Hanxiang Zeng, Ruimao Hua*

Palladium-Catalyzed Hydrophenylation of Alkyne with Sodium Tetraphenylborate under Mild Conditions.

The Journal of Organic Chemistry 2008, 73, 558-562

学术论文章节编著

(1)  著者:“Recent Advances in Organocatalysis” 一书 (2016年InTech出版社出版;主编:Iyad Karame & Hassan Srour) 第5章:“Organocatalytic Transformation of Carbon Dioxide”

(2)  著者:“Copper-Mediated Cross-Coupling Reactions” 一书 (2013年Wiley出版社出版;主编:Gwilherm Evano & Nicolas Blanchard) 第12章:“Copper-Catalyzed Alkynylation and Alkenylation Reaction of Alkynyl Derivatives: New Access to Diynes and Enynes”

(3)  客座编辑:Current Organic Chemistry, 2011年第15卷第5期特刊: Recent Progress in the Synthesis and Applications of Cyclic Compounds

(4)  著者:2008年化学工业出版社出版的《现代有机反应》丛书,第五卷 “金属催化反应”中的“Sonogashira Reaction” 和 “Ullmann Reaction”两章。

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